Most plugins (with very few exceptions) store their plugin data in a format that is identical in both 32-bit and 64-bit versions, so yes, simply give it a try, Kontakt should be able to load your settings in the 64-bit version as well. And even if it doesn't, you can also use the plugin bridge in the 32-bit version and explicitely bridge the 32-bit version of Kontakt (and disable "share bridge instance" so that every bridged instance has its own memory space).
EDIT: And to re-iterate what is being said on the download site and wiki: If you use a lot of 32-bit plugins which are not available as 64-bit plugins, the approach above is better than switching to the x64 version entirely, because then you'd have to bridge all those other plugins, and every bridged plugin adds latency. So if the majority of plugins you use is available as 64-bit plugins, the 64-bit version will be optimal for you. On the other hand, if the majority of plugins is only available as 32-bit plugins, it would be better to keep using the 32-bit version and only run Kontakt in the plugin bridge in its own process with its own 4GB of memory per instance.